Physicists from the University of Texas Dallas have published new findings examining the electrical properties of materials that could be harnessed for next-generation transistors and electronics. Dr. Fan Zhang, assistant professor of physics, and senior physics student Armin Khamoshi recently published their research on transition metal dichalcogenides, or TMDs.
In recent years, scientists and engineers have become interested in TMDs in part because they are superior in many ways to graphene, which is a one-atom thick, two-dimensional sheet of carbon atoms arranged in a lattice. Since it was first isolated in 2004, graphene has been investigated for its potential to replace conventional semiconductors in transistors, shrinking them even further in size. Graphene is an exceptional conductor, a material in which electrons move easily, with high mobility.
It was thought that graphene could be used in transistors, but in transistors, you need to be able to switch the electric current on and off. With graphene, however, the current cannot be easily switched off. In their search for alternatives, scientists and engineers have turned to TMDs, which also can be made into thin, two-dimensional sheets, or monolayers, just a few molecules thick.
TMDs have something graphene does not have - an energy gap that allows the flow of electrons to be controlled, for the current to be switched on and off. This gap makes TMDs ideal for use in transistors. TMDs are also very good absorbers of circularly polarized light, so they could be used in detectors. For these reasons, these materials have become a very popular topic of research. One of the challenges is to optimize and increase electron mobility in TMD materials, a key factor if they are to be developed for use in transistors.
In their most recent project, Zhang and Khamoshi provided the theoretical work to guide the Hong Kong group on the layer-by-layer construction of a TMD device and on the use of magnetic fields to study how electrons travel through the device. Each monolayer of TMD is three molecules thick, and the layers were sandwiched between two sheets of boron nitride molecules.
The behavior of electrons controls the behavior of these materials. Researchers want to make use of highly mobile electrons, but it is very challenging. The team discovered that how electrons behave in the TMDs depends on whether an even or odd number of TMD layers were used. This layer-dependent behavior is a very surprising finding. It doesn't matter how many layers you have, but rather, whether there are an odd or even number of layers.
Because the TMD materials operate on the scale of individual atoms and electrons, the researchers incorporated quantum physics into their theories and observations. Unlike classical physics, which describes the behavior of large-scale objects that we can see and touch, quantum physics governs the realm of very small particles, including electrons.
On the size scale of everyday electrical devices, electrons flowing through wires behave like a stream of particles. In the quantum world, however, electrons behave like waves, and the electrical transverse conductance of the two-dimensional material in the presence of a magnetic field is no longer like a stream—it changes in discrete steps. The phenomenon is called quantum Hall conductance.
Quantum Hall conductance might change one step by one step, or two steps by two steps, and so on. Physicists found that if they used an even number of TMD layers in their device, there was a 12-step quantum conductance. If they applied a strong enough magnetic field to it, it would change by six steps at a time.
Using an odd number of layers combined with a low magnetic field also resulted in a 6-step quantum Hall conductance in the TMDs, but under stronger magnetic fields, it became a 3-step by 3-step phenomenon. These results not only decipher the intrinsic properties of TMD materials, but also demonstrate that they achieved high electron mobility in the devices. This gives hope that scientists can one day use TMDs for transistors.
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